Search results for "Diazocine derivative"

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(E)-2-{[1-(3,11-Dimethyl-4-methylene-10-oxo-1-phenyl-4,5,10,11-tetrahydro-1H-benzo[b]pyrazolo[3,4-f][1,5]diazocin-5-yl)ethylidene]amino}-N-methyl-N-(…

2013

The central eight-membered ring of the title compound, C40H36N8O2, deviates from the ideal boat conformation because the bond between the exo-ethylene group and the adjacent N atom is twisted by 60.0 (4)° due to steric hindrance. Its adjacent benzene and pyrazole rings are oriented almost perpendicular to each other, making a dihedral angle of 85.8 (3)°. In the crystal, the molecules are linked by C(ar)—H...O hydrogen bonds, generating a three-dimensional network.

Steric effectsCrystallographyHydrogen bondCyclohexane conformationGeneral ChemistryDihedral anglePyrazoleCondensed Matter PhysicsRing (chemistry)Settore CHIM/08 - Chimica FarmaceuticaOrganic PapersMedicinal chemistrychemistry.chemical_compoundchemistryDiazocine derivative X-ray structureQD901-999General Materials ScienceDiazoEne reactionActa Crystallographica Section E Structure Reports Online
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